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There are three isomers of phthalic acid: Orthophthalic acid (1,2 - benzenedicarboxylic acid), Isophthalic acid (1,3 -), and Terephthalic acid (1,4 -). Each phthalic isomer has particular advantages and liabilities when used in polyester production. The properties of terephthalic are generally better than orthopolyesters and are often quite similar to those of isopolyesters. Terepolyesters generally have a higher heat deflection temperature. Terephthalic acid is the slowest reacting of the three phthalic acids. Catalysts or pressure are required to esterify terephthalic acid within a reasonable time period. Terephthalic polyesters made with primary glycols such as neopentyl have poor styrene tolerance compared with ortho and isopolyesters. Most physical properties are not substantially different than 1:1 isopolyesters. The most dramatic differences are the higher heat deflection temperature and lower hardness of the terephthalate polyesters. Isopolyesters are about 15 percent tougher than equivalent terepolyesters. The applications for Terephthalates are the same as for Isophthalates but at a compromise with regards to lower hardness as compared to Isophthalates. # TEREPHTHALATES for * applications requiring higher mechanical Strength and good chemical properties. |