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There are three isomers of phthalic acid: Orthophthalic acid (1,2- benzenedicarboxylic acid), Isophthalic acid (1,3-) and Terephthalic acid (1,4-). Orthophthalic acid , the only one of the three that can form an anhydride, is normally used in that form. Each phthalic isomer has particular advantages and liabilities when used in polyester production. The ortho isomer is normally used as the anhydride which reacts faster initially and releases one, rather than two moles of esterification water. Orthophthalic resins are low molecular weight materials having relatively higher water solubility and reduced corrosion resistance. These resins are rarely processed to the same molecular weight as isophthalic and terephthalic based resins. Those that are specially processed to the molecular weight range easily attained with isophthalic acid, are susceptible to premature gelation and may contain low molecular weight species. Several factors cause the lower resistance of orthopolyesters to attack by aqueous solutions. The orthophthalate ester linkages are more visible, hence are more susceptible to attack than the ester linkages of isopolyesters. The hydrolytic stability of orthopolyesters is far inferior to that of isopolyesters. Orthopolyesters are cheaper to produce than isopolyesters or tere-polyesters due to raw material costs, processing costs and ancillary costs. This is one single large reason why orthopolyesters are favourites in the moulding industry. However, customer oriented cost analysis must include not only resin purchase price and fabrication costs, but life-cycle cost factors such as maintenance, useful life before replacement and performance in multiple environments. Orthophthalates are used for a wide variety of applications. Some of the applications for which Dipol Orthopolyesters are used, are as follows: # ORTHOPHTHALATES for * Potting and Encapsulation of Electrical & Electronic components * General Purpose Laminating resins * Resilient Cultured Marble grade * Quick setting Button grade Casting resins * Optically clear Casting resins * Translucent UV stabilized Rooflight grade * Neo Pentyl Glycol modified Marine grade * Low viscosity Resin Transfer Moulding and Spray Up resins * Medium to high reactive Pultrusion grade * High reactive resin for Low shrink Sheet Moulding / Dough Moulding compounds
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