| CHEMICAL & CORROSION RESISTANCE |
| |
Composites are widely used in chemical plant applications because of their excellent chemical resistance properties. The performance of equipment in severe corrosion service depends on a clear definition of the process, corrosion and the service conditions. Therefore when reviewing a project, the following issues must be addressed: |
|
|
| |
|
|
What type of chemicals must the equipment resist and in what concentrations? |
|
Are there any trace contaminants in the process stream? |
|
What temperature limits and fluctuations are involved? |
|
Will it be subject to pressure or vacuum loading? |
|
Must the equipment comply with FDA food regulations? |
|
Are there any fire retardance / flame spread requirements? |
|
What are the external environmental conditions? |
|
 |
The Following table lists general chemical resistance information on composites in comparison with various metals / alloys. This data is of a general nature only, and should not be used for final equipment selection without consultation with your fabricator and resin supplier. |
|
| |
GUIDE TO CHEMICAL RESISTANCE OF COMPOSITES MADE WITH ISOPHTHALIC, BISPHENOL AND VINYL ESTER RESINS COMPARED TO COMPETITIVE MATERIALS. |
| |
| ..........R = Resistant, NR = Not Resistant.......... |
| |
Material |
Carbon
Steel
1020 |
Stainless
Steel
316 |
Hastealloy
C |
Alum. |
FRP
Isophthalic |
FRP
Bisphenol |
FRP
Vinylester |
Sulphuric Acid (Dil) |
NR |
R to 5% |
R |
NR |
R |
R |
R |
Sulphuric Acid (Conc.) |
R |
R |
R |
NR |
R |
R |
R |
Hydrochoric Acid (Dil) |
NR |
NR |
R |
NR |
R |
R |
R |
Hydrochoric Acid (Conc.) |
NR |
NR |
R |
NR |
NR |
R |
R |
Hydrochoric Acid |
NR |
NR |
R |
NR |
NR |
R |
R |
Phospheric Acid (Dil) |
NR |
R |
R |
NR |
R |
R |
R |
Phospheric Acid (Conc.) |
NR |
R |
R |
NR |
NR |
R |
R |
Caustic Soda (Dil) |
R |
R |
R |
NR |
NR |
R |
R |
Caustic Soda (Conc.) |
R |
NR |
R |
NR |
NR |
R |
R |
Acid Chloride Salts |
NR |
NR |
R |
NR |
R |
R |
R |
Bleach |
NR |
NR |
R |
NR |
NR |
R to 5% |
R |
Wet Chlorine |
NR |
NR |
R |
NR |
NR |
R to 70%C |
R |
Nitric Acid |
NR |
NR |
R |
NR |
NR |
R to 40% |
R to 40% |
|
| |
APPLICATIONS |
Bore Casings, Chimneys, Covers & Hoods, Cyclones, Drainage Channels, Ducting, Flooring, Fume Cupboards, Fume Stacks, Gratings, Ladders, Linings-Pipes & Tanks, Mist Eliminators, Pipes & Tubes, Pollution Control Equipments, Pressure Vessels, Process Vessels, Pumps, Railing, Scrubbers, Sewage Treatment, Structural Beams, Stacks, Tanks-General, Tanks-Fuel, Tanks-Underground, Valves, Vents, Water Treatment |
|
| RECOMMENDED RESINS |
|
Dipol ISOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAXIMUM LIMITING TEMPERAURE UPTO 90°C. |
| |
|
|
Dipol BISPHENOL RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAXIMUM LIMITING TEMPERATURE UPTO 100°C. |
| |
|
|
Dipol VINYL ESTER RESINS, GELCOATS & FIRE RETARDANT GRADES |
| |
(A) STANDARD GRADE FOR MAX. TEMP. UPTO 100°C.
(B) SUPERIOR GRADE FOR MAX. TEMP. UPTO 130°C |
| |
|
|
(Above chart is only a partial list of recommendations . Please refer to exhaustive Chemical Resistance Chart available with us for Recommended resins for use with specific chemicals. In any case, it is advisable to seek the recommendations of your consultants before selecting a resin system.) |
|
| BUILDING & CIVIL CONSTRUCTION |
| |
Composites by virtue of its light weight, strength, impact resistance and durability makes them ideally suited for the manufacture of prefabricated, portable and modular buildings as well as for exterior cladding panels, which can simulate masonary or stone. The recent availability of highly fire resistant phenolic composites opens up a new market for composites in building applications. The total potential for structural applications in building application has scarcely been tapped compared to the matured chemical & corrosion resistant application market. It is possible to make single run or multiple run architectural applications economically due to the versatility and durability of composites. |
| |
The flexibility of FRP composites creates unlimited applications in building components, bridges, marine/waterfront environments, tanks and pipes, and other endless applications. The complexity of FRP material composition such as type of fibers, resins, volume fractions and fiber orientations can greatly influence the performance of the structure. Advantages of using FRP composites for infrastructure applications are: light-weight, high tensile strength, ease of installation (no heavy construction/erection equipment) and corrosion resistance. An optimized design and prefabrication (or partial prefabrication) at the manufacturer can reduce the number of parts and reduce transportation costs. |
|
|
| |
Typical application of FRP composites in building components include beams, columns, roof trusses, roofing, purlins and sidings. Most FRP composite buildings are used in corrosive environments or located where electromagnetic transparency for antenna housing applications is the main design parameters. |
| |
Green houses made with composites gives benefits not available with alternative materials of construction. Compared to lower priced poly film-over-frame configurations and traditional greenhouses with glass or thermoplastic glazing, composites will not tear and is longer-lasting. Life expectancy of the composite structure is at least 20 years. Composites used in greenhouses outperforms both glass and thermoplastics in its ability to provide the highest quality, most productive lighting. It is more resistant to impact a from hail and other damage like a fallen limb, etc. Unlike rot-prone wood and rust-prone metal, the composite will not deteriorate from exposure to the elements on the outside and the moist greenhouse environment on the inside. Glass fiber reinforced polyester also gives the greenhouse high thermal insulation values for excellent temperature control. |
| |
|
Doors and Window lineals made from glass fiber reinforced polyester composite have excellent dimensional stability over a wide range of environmental conditions. The composite maintains its precise shape in heat or cold, dry or humid weather. It will not rot like wood and has higher impact strength values than vinyl. They also provide high thermal insulation values thereby reducing energy costs by helping to retain the air-conditioned or heated environment. |
|
|
High strength, lightweight glass fiber composite Bath/Shower and other plumbing components provide ease of installation and are not affected by hot soapy water. Unlike porcelain and steel, the composite surface is warm to the touch. Molding with composite, allows for more aesthetic shapes, smoother surface finishes, less mildew and easy cleaning. |
| |
There are many other exciting developments that may become the wave of the future in buildings and in civil applications. The Chinese have built an all-glass composite pedestrian bridge in Beijing. Both in the U.S. and in Europe, composite pre- and post-tensioned concrete reinforcements are under evaluation and long term feasibility studies are underway. Compared to steel, composite reinforcing bars (rebar) for concrete are lighter in weight and inherently resist the destructive effects of moisture and road salts. According to Marshall Industries,Lima, Ohio, USA, compared to epoxy-coated steel rebar, the new composite rebar has twice the tensile strength at one-fourth the weight. In addition, the composite rebar's co-efficient of thermal expansio is closer to concrete than that of steel. Because the composite has a low dielectric constant, it is suited for applications requiring magnetic transparency. These include concrete foundations for magnetic resonance imaging (MRI) facilities, aircraft compass calibration pads and computer and laser testing facilities. |
| |
| APPLICATIONS : |
Architectural Mouldings, Ballistic Panels, Baths & Basins, Buildings - Portable & Modular, Claddings, Cabinets, Domes, Drainage Channels, Drainage Pits, Farm Buildings, Formwork, Ponds & Fountains, Sinks, Septic Tanks, Sheeting - Roof & Flat, Shower Trays, Shower Enclosures, Structural Members, Troughs, Toilet Portable, Vanity Units, Water Tanks,....... |
| |
RECOMMENDED RESINS: |
|
Dipol ORTHOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAJOR APLICATIONS. |
|
Dipol ISOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR BETTER STRENGTH & WEATHERABILITY |
|
|
| TRANSPORTATION |
| |
One of the better illustrations of the versatility of design and performance achievable with composites, is in the field of transportation. Composites play a very important role in the development of modern fuel efficient commercial cars, mass transit systems, passenger jetliners as well as high performance military aircrafts by their lightweight, fatigue resistance and other extremes of engineering requirements which are all readily accommodated by skillful design in composites. In the mass transit area, assembly and maintenance costs can be dramatically reduced through the use of single piece moldings in trains and buses, with the added benefit of inbuilt fire resistance when required. The recent development of new low pressure molding compounds capable of achieving an "A Class" surface finish opens up new opportunities for the mass production of light weight automotive components as the emphasis on more fuel efficient motor vehicles gathers further momentum. Sandwich panel construction utilising a foam core to provide rigidity and insulation between inner and outer composite laminates, is widely used for the manufacture of refrigerated vans, truck bodies and refrigerated containers. |
|
|
|
Composites applications in trains are growing as rail operators come under growing pressure to reduce the operating costs of their rolling stock. Composites have two attractive advantages over metal: they can help reduce weight, which leads to lower fuel consumption and other benefits; and they offer lower maintenance requirements compared with metal parts which corrode over time. Composites are already being used to good effect in interior parts such as control panels, wall and ceiling panels, luggage compartments, partitioning walls and on exteriors in roofs, fronts and skirts. Composites are good materials for bonding and in addition, the large , thin composites panels do not dent or bend like metal. The sound damping properties of composites are a further benefit, which makes the train quieter, both for the passengers and to the outside world. The "TALENT" train in Germany has opted for pultruded side walls over both metal and moulded pultrusions. |
| |
|
The automotive market will continue to be the major purchaser of composites in U.S. and in Europe. Use of bumper beams and springs, already in production, will expand. Composite wheels have been introduced on several production vehicles and their use will expand, responding to the demand for performance and styling. There are more than 400 Sheet moulding compound applications in nearly 130 vehicles in the U.S. Body panels continue to predominate, although there is a growing number of structural components in production. |
|
|
There are many other developments that may become the wave of the future. The "Voyager" set the "around-the-world-without-refueling" record using a composite structure. This "one of a kind" aircraft brought fresh attention to composites and demonstrated the exiting new potential for advances in aircraft structure. The Beech Starship now has FAA certification. It represents the first all-composite production commercial aircraft. The "Stealth" aircraft technology brings attention to the radar transparency and structural performance of composites. The use of composites will undoubtedly increase on all types of military and commercial aircraft. |
| |
| APPLICATIONS : |
| Aircraft / Aerospace, Automotive, Aerodynamic Devices, Buses, Mass Transit Systems, Fuel Tanks, Heat Shields, Military Vehicles, Motor Cycles, Railways, Refrigerated Vans & Truck Bodies, Refrigerated Containers, Sledges, Tankers, Trucks,........... |
| |
RECOMMENDED RESINS: |
|
Dipol ORTHOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAJOR APPLICATIONS |
|
Dipol ISOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR BETTER STRENGTH, RESISTANCE TO CORROSION & WEATHERABILITY. |
|
Dipol VINYL ESTER RESINS, GELCOATS & FIRE RETARDANT GRADES FOR ELEVATED TEMPERATURES AND HIGHER STRENGTH & FLEXIBILITY. |
|
|
| MARINE & OFFSHORE |
| |
The harsh environmental conditions coupled by the severe corrosion caused due to the saline conditions has prompted many boat/ship builders to increasingly turn to composites as a solution. Naval architects today are being asked to provide a new and faster breed of ship. The latest ferries and increasingly other ships too, are low weight, highly stressed structures relying on dynamic lift to achieve speeds of 40 to 60 knots or more. Boats made with marine grade resins offer superior strength-to-weight ratios, impact resistance and cosmetic properties. Modern offshore racing boats are subjected to extreme slamming loads comparable with those experienced by power boats and these are now almost entirely made in composites using either glass fibers or carbon fibers as reinforcements in addition to Isophthalic resin which is now the Industry standard and in many cases expensive Vinyl ester resins. Mine hunters are now being fabricated in composites for their superior non-magnetic properties and excellent weather ability besides their capability to absorb the tremendous impact of a nearby detonation. The twelve meter yachts used in racing, which is conducted close to shore in limited wind speed ranges, have dramatically different performance requirements to round-the-world racing yachts which must be able to withstand gale force conditions for long periods in regions where prospects of rescue are uncertain. The marine industry has produced a wide array of glass fiber products that reduce maintenance and offer easy repair. Pleasure boats of all typed rely on glass fiber for lighter weight and durability. Fishing boats operating off the Alaskan coast for as long as 30 years have proven the cold water performance of glass fiber hulls and have also withstood the constant pounding on the rocks of the rugged shoreline. |
|
|
| |
One of the major advantages of composites becomes clear as soon as offshore engineers start making their buoyancy calculations. Future platforms of the floating type will require enough buoyancy to support their own weight and that of all the processing equipment they carry, and to bear the submerged weight of the risers - pipes rising from the well heads on the sea beds to the platform at the surface. Composites have the potential to replace many other steel pipes and `tubulars' used in the offshore industry. Applications in non-critical load bearing structures, such as gratings and handrails, have become common-place and there are few barriers to use in these areas. Pipes above water, on the platforms themselves, can also be usefully made for composites. In the Gulf of Mexico, for example, over 30 kms of composite piping was installed during a recent three-year period. Using composite pipe for the fire drenching system on one platform alone, saved a offshore platform, an estimated 72 tonnes in weight. A Norwegian research Institute considers that up to half of the many steel tanks, accumulators and other vessels found on the average platform could be substituted by composite equivalents weighing 30 % less. When engineers designed, from stratch, a modest facility having the capability of a present standard Davy monotower platform, taking full advantage of composites, they found that primary structure weight was reduced from the 187 tonnes for the steel platform to just 84 tonnes, with fabricated cost being reduced by a quarter. |
|
| |
| APPLICATIONS : |
| Marine boats, canoes, trawlers, ships, mine hunters, recreational paddle boats, kayaks, speedboats, floats, life-buoys, light-houses, docks, piers, gratings on offshore platforms, structural profiles, handrails, ladders, cabins, modular buildings, helipads, dish antennas, sonar domes, radomes. |
|
RECOMMENDED RESINS: |
|
Dipol NPG BASED ISOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAJOR APPLICATIONS. |
|
Dipol VINYL ESTER RESINS, GELCOATS & FIRE RETARDANT GRADES FOR SPECIALIZED APPLICATIONS. |
|
|
ENGINEERING, INDUSTRIAL & APPLIANCES |
| |
The light weight, excellent electrical properties as well as high strength, corrosion resistance, resistance to vandalism and versatility of composites has endured themselves to use in the Engineering and Industrial fields which is reporting an increasing number of applications. |
|
|
| |
The ability of glass reinforced polyesters to withstand high temperatures combined with mouldability and easy processability, has led to its selection for use in high heat resistant knobs for commercial ovens. |
| |
Composites are used for making Tool handles which provide far more strength, quality and durability than wood at a lower weight. The composite handle is also impervious to rotting, warpage and corrosion. Because the composite has inherent electrical insulating properties and will not absorb moisture like wood, the handle provides more protection against accidental electrical shock. |
| |
A glass fiber reinforced composite is providing strength, stiffness, impact resistance and dimensional stability for the housing of Black and Decker's Hammer Plus, pneumatic drill. Composites find use in Hand held Sander bearing caps by reducing costs over metal caps and with standing high speeds, high temperatures and vibration and not relaxing over a period of time. It is also strong enough to prevent cracking. |
| |
Power stations benefit from using fiberglass cooling towers which eliminates the use of preservative treatment which is normally associated with wooden structural towers and therefore eliminates the possibility of any preservative potentially leaching into the ground water. |
| |
Endoscopy workstation's major components are being made from polyester-based sheet and bulk-moulding compounds (SMC/BMC), and requires limited secondary finishing which helps to speed up production and assembly. The multi-function workstation now in daily use in many hospitals throughout the world, is said to provide a strong, mobile and lightweight trolley, housing a wide variety of endoscopy instruments and equipment and reduces the number of trolley variants and clutter in an endoscopy theatre. |
| |
Helmets made from FRP find favour in recreational sports, firefighters and in military besides other industrial applications. |
|
|
| |
| APPLICATIONS : |
Air conditioning Towers, Agricultural Products, Irrigation products, Beams, Battens, Bins, covers, Floorings, Cabinets & Boxes, Ducts, Electrical, Gratings, Pipes, Insulators, Helmets, Heat Shields, Housings, Ladders, Mine Ducts & Vents, Mining-Rock Anchors, Mineral Processing, Mining Equipments, Panels-Sandwich, Pits, Poles & Posts, Polymer Concrete, Pontoons, Pollution Control equipments, pressure Vessels, Radomes, Rails... |
| |
RECOMMENDED RESINS: |
|
Dipol ORTHOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR MAJOR APPLICATIONS. |
|
Dipol ISOPHTHALIC RESINS, GELCOATS & FIRE RETARDANT GRADES FOR BETTER STRENGTH AND RESISTANCE TO CORROSION. |
|
Dipol VINYL ESTER RESINS, GELCOATS & FIRE RETARDANT GRADES FOR ELEVATED TEMPERATURES AND HIGHER TENSILE & ELONGATION PROPERTIES. |
|
|
TELECOMMUNICATIONS, ELECTRICALS & ELECTRONICS |
| |
The demand for material of construction with excellent electrical, high and low voltage insulation properties, corrosion resistance and incorporation of anti static properties are met by Composites. A range of fabrication processes including compression moulding, filament winding, resin transfer moulding and formed laminate sheets are used for fabrication of electrical components. |
|
|
| |
In the electrical and electronics industries, the outstanding electrical resistance properties of glass fiber products offer broad choices for manufacturers of wiring devices, printed circuit boards and satellite parabolic antennas. |
| |
The durability, weather ability, structural support and high dielectric strength are primary reasons why more and more composites applications are being developed to meet the stringent demands across every industry segment utilizing electrical/electronic technology. |
| |
Outdoor lighting fixtures made from FRP are cheaper to make and require less maintenance than their metal equivalents. Although the fixtures can become quite hot, the composite has a continuous use temperature of 155°C safely above the 140°C required. Other factors in the composite's favour are good dimensional stability and property retention, including stability to ultraviolet (UV) light, when exposed to outdoor conditions. The composite product also saves money. Switching from die cast aluminum to a composite, manufacturers can eliminate all machining operations. In additions, the fixtures can be moulded in required colours by pigmenting the resin, which eliminates the need for further painting. |
|
Unlike wood, composite cross arms for power distribution are not affected by insects, vermin, woodpeckers and rotting. Composite crossarms used in conjunction with composite poles, allow the power array to be more compact. A tighter array reduces the range of the electromagnetic field (EMF) normally created by live electric wires. A more compact array also allows utilities to carry more power without having to expand their rights-of-way. Telephone and Lighting Poles made from composites are light enough to be transported by small helicopter and installed without expensive heavy equipment. The poles can be installed directly into the ground because the composite resists rotting and corrosion. This application also benefits from composite's electrical insulating properties. |
|
|
| |
Large weight-bearing power transmission towers have been build near Los Angeles in U.S. using composite. The result is lower construction and maintenance costs, minimal environmental impact and smaller electromagnetic fields. |
| |
Composites contribute to the high efficiency of rotor blades for wind energy converters. Composites can be aerodynamically shaped to take optimal advantage of the wind's potential. Besides light weight, high strength and design flexibility, the efficiency of composites for this application is also evident in the material's inherent vibration-damping characteristics, reduction in drag and enhanced corrosion and fatigue resistance. |
| |
 |
High resolution digital television (DTV) is coming, bringing with it a need for new antennas to accommodate the switch from conventional transmission systems. Broadcast antennas are subject to all the vagaries of the local climate, whether it be high heat and humidity, snow and sleet or both. Radomes which protect these antennas, are made from isopolyesters which is an ideal material due to its transparency to broadcast signals besides superior corrosion and moisture resistance thereby providing the durability to stand up to all weather extremes. Isopolyester's favourable strength-to-weight ratio gives the radome the strength needed to stand up to strong winds while making for easier installation. They also provide good UV resistance for excellent protection from sun degradation. |
|
|
| |
| APPLICATIONS: |
Electrical Cabinet boxes, Fuse boxes, Miniature Circuit Breakers, Switches, Bus bars, Insulators, Electrical Transmission Towers, Light Poles, Telecommunication Poles, Cross-bars, strength members for Optical Fiber Cables, Junction boxes, Isolators, Safety Ladders, Earthing & Discharging rods, Dish antennas,....... |
| |
RECOMMENDED RESINS: |
|
Dipol ORTHOPHTHALIC RESINS & FIRE RETARDANT GRADES FOR MAJOR APPLICATIONS. |
|
Dipol ISOPHTHALIC RESINS FOR BETTER STRENGTH |
|
|
RECREATIONAL, SPORTING & CONSUMER DURABLES |
| |
|
Composites are the preferred long lasting construction medium for a wide range of sporting and recreational vehicles including gliders, sailboats, canoes, caravans and power boats. The free form design flexibility at low cost provided by composites are ideal for the manufacture of garden ponds and fountains, swimming pools and many other applications requiring single run applications. Glass fiber composite baseball bats replace often-broken wood and maintain the balance, whip and feel of a traditional bat. Ski manufacturers use glass fiber composites for their inherent thermal properties to assure proper camber in temperature changes. Again, weight, flexibility and durability offer key advantages for enhancing performance and enjoyment. Fishing rods of pultruded glass fibers are highly flexible and extremely strong. Likewise, light weight but flexible and strong hockey sticks show that wood is not all it's cracked-up to be by taking the punishment of the tough sport while providing the finesse needed for shooting accuracy. Tough glass fiber composites enhance the way we play by strengthening almost every type of recreational product. |
|
| |
Reinforced plastics have a long history in limited production sports and racing cars to reduce weight. In today's premier motor racing competition, sophisticated carbon fiber composites are used to make the light weight, high strength bodywork required for cars that reach speeds above 250 km/hour and yet must withstand stringent crash tests. The car's components are designed to be as light as possible whilst satisfying such criteria as stiffness, strength, service temperature, damage tolerance and vibration resistance. |
|
|
| |
Composite bike frames and rims are finding favour with cycle racing teams due to high strength and a fatigue life ten times greater than that of aluminum coupled with 25 % weight reduction. |
| |
|
There is no yachting contest more demanding than the single-handed, round-the-world race. Racing at speeds of up to 50 km/hour, in lightly-built, high-tech planning boats is a feat far beyond typical recreational yachting. Add to this the severe weather the participants are likely to encounter and you have the ultimate challenge for sailor, builder and designer. Hulls made from composites with a balsa wood core and decks, spars, rudders and canopy made in composites result in a very light yet rugged boat, which is capable of extreme speeds, with a degree of safety. |
|
|
| |
| APPLICATIONS : |
Boats - Canoes/Kayaks, Boats - Sail & Power, Caravans, Furniture - Outdoor, Furniture - Others, Helmets - Sporting, Hockey, etc sticks, horse Floats, Playground Equipments, Ponds & Fountains, Pools & Spas, Pool Slides, Sail Battens, Skis, Oars, Paddles, Sporting Equipments, Swimming Pool Filters, Surf Boards, Gliders,....... |
| |
RECOMMENDED RESINS: |
|
Dipol ORTHOPHTHALATES FOR ALL MAJOR APPLICATIONS |
|
Dipol NPG BASED ISOPHTHALATES FOR MARINE AND OUTDOOR APPLICATIONS |
|
Dipol VINYLESTERS FOR APPLICATIONS REQUIRING HIGHER STRENGTH AND FLEXIBILITY. |
|
| |
|